acyclic diene metathesis admet polymerization



Die acyclische Dienmetathese-Polymerisation (englisch acyclic diene metathesis), auch ADMET-Polymerisation genannt, ist eine Variante der Alkenmetathese, bei der Diolefine mit endständigen Doppelbindungen (α,ω-Diene) in einer als Stufenwachstumsreaktion ablaufenden Gleichgewichtsreaktion in Gegenwart von
Acyclic diene metathesis or 'ADMET' (distinguish from ADME) is a special type of olefin metathesis used to polymerize terminal dienes to polyenes: ADMET. The new double bonds formed can be in cis- or trans-configuration, the exact ratio depends on the monomer and catalyst structures. It is a type of step-growth,
01.05.1991 -
4 Acyclic Diene Metathesis (ADMET) Polymerization. Tammy A. Davidson and Kenneth B. Wagener. The George and Josephine Butler Polymer Research Laboratory, Department of Chemistry and Center for Macromolecular Science and Engineering, University of Florida, Gaines- ville, FL, U.S.A.. List of Symbols and
Abstract. The history of and major advances in the acyclic diene metathesis (ADMET) reaction are described. Because precise branch identity and frequency can be achieved by ADMET polymerizations of symmetrical α,ω-dienes, polyethylenes with precisely spaced alkyl branches of specified length have been prepared.
Abstract. Dienes can undergo olefin metathesis reactions of two types: (i) intermolecular, and (ii) intramolecular. Intramolecular metathesis (RCM) reactions occur with great readiness henever the product is a 6-membered ring. They are also often favoured for the production of 5-, 7-, and 8-membered rings, depending on
23.09.2009 -
30.03.2015 -
Acyclic Diene Metathesis (ADMET) polymerization was established decades ago and has since developed into a robust and reliable technique. A wide range of different, new materials exhibiting unique properties has been produced via ADMET polymerization since its development. This versatile technique allows, through

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